Abstract
Polycyclic aromatic hydrocarbon (PAH) molecules are abundant and widespread throughout the Universe, as revealed by their distinctive set of emission bands at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 μm, which are characteristic of their vibrational modes. They are ubiquitously seen in a wide variety of astrophysical regions, ranging from planet-forming disks around young stars to the interstellar medium of the Milky Way and other galaxies out to high redshifts at z ≳ 4. PAHs profoundly influence the thermal budget and chemistry of the interstellar medium by dominating the photoelectric heating of the gas and controlling the ionization balance. Here I review the current state of knowledge of the astrophysics of PAHs, focusing on their observational characteristics obtained from the Spitzer Space Telescope and their diagnostic power for probing the local physical and chemical conditions and processes. Special attention is paid to the spectral properties of PAHs and their variations revealed by the Infrared Spectrograph onboard Spitzer across a much broader range of extragalactic environments (for example, distant galaxies, early-type galaxies, galactic halos, active galactic nuclei and low-metallicity galaxies) than was previously possible with the Infrared Space Observatory or any other telescope facilities. Also highlighted is the relation between the PAH abundance and the galaxy metallicity established for the first time by Spitzer.
This is a preview of subscription content, access via your institution
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$29.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 digital issues and online access to articles
$119.00 per year
only $9.92 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Gillett, F. C., Forrest, W. J. & Merrill, K. M. 8–13 μm spectra of NGC 7027, BD+30 3639, and NGC 6572. Astrophys. J. 183, 87–93 (1973).
Merrill, K. M., Soifer, B. T. & Russell, R. W. The 2–4 μm spectrum of NGC 7027. Astrophys. J. 200, L37–L39 (1975).
Russell, R. W., Soifer, B. T. & Willner, S. P. The 4–8 μm spectrum of NGC 7027. Astrophys. J. 217, L149–L153 (1977).
Willner, S. P., Soifer, B. T., Russell, R. W., Joyce, R. R. & Gillett, F. C. 2–8 μm spectrophotometry of M82. Astrophys. J. 217, L121–L124 (1977).
Léger, A. & Puget, J. L. Identification of the “unidentified” IR emission features of interstellar dust? Astron. Astrophys. 137, L5–L8 (1984).
Allamandola, L. J., Tielens, A. G. G. M. & Baker, J. R. Polycyclic aromatic hydrocarbons and the unidentified infrared emission bands: Auto exhaust along the Milky Way. Astrophys. J. 290, L25–L28 (1985).
Allamandola, L. J., Tielens, A. G. G. M. & Baker, J. R. Interstellar polycyclic aromatic hydrocarbons: the infrared emission bands, the excitation/emission mechanism, and the astrophysical implications. Astrophys. J. Suppl. 71, 733–775 (1989).
Draine, B. T. & Li, A. Infrared emission from interstellar dust. I. Stochastic heating of small grains. Astrophys. J. 551, 807–824 (2001).
Li, A. & Draine, B. T. Infrared emission from interstellar dust. II. The diffuse interstellar medium. Astrophys. J. 554, 778–802 (2001).
Draine, B. T. & Li, A. Infrared emission from interstellar dust. IV. The silicate–graphite–PAH model in the post-Spitzer era. Astrophys. J. 657, 810–837 (2007).
Zubko, V., Dwek, E. & Arendt, R. G. Interstellar dust models consistent with extinction, emission, and abundance constraints. Astrophys. J. Suppl. 152, 211–249 (2004).
Siebenmorgen, R., Voshchinnikov, N. V. & Bagnulo, S. Dust in the diffuse interstellar medium. Extinction, emission, linear and circular polarisation. Astron. Astrophys. 561, A82 (2014).
Jones, A. P., Köhler, M., Ysard, N., Bocchio, M. & Verstraete, L. The global dust modelling framework THEMIS. Astron. Astrophys. 602, A46 (2017).
Smith, J. D. T. et al. The mid-infrared spectrum of star-forming galaxies: global properties of polycyclic aromatic hydrocarbon emission. Astrophys. J. 656, 770–791 (2007).
Tielens, A. G. G. M. Interstellar polycyclic aromatic hydrocarbon molecules. Annu. Rev. Astron. Astrophys. 46, 289–337 (2008).
Joblin, C., Léger, A. & Martin, P. Contribution of polycyclic aromatic hydrocarbon molecules to the interstellar extinction curve. Astrophys. J. 393, L79–L82 (1992).
Cecchi-Pestellini, C., Malloci, G., Joblin, C. & Williams, D. A. The role of the charge state of PAHs in ultraviolet extinction. Astron. Astrophys. 486, 25–29 (2008).
Mulas, G., Zonca, A., Casu, S. & Cecchi-Pestellini, C. Modeling galactic extinction with dust and “real” polycyclic aromatic hydrocarbons. Astrophys. J. Suppl. 207, 7 (2013).
Steglich, M. et al. Electronic spectroscopy of medium-sized polycyclic aromatic hydrocarbons: implications for the carriers of the 2175 Å UV bump. Astrophys. J. 712, L16–L20 (2011).
Salama, F. et al. Polycyclic aromatic hydrocarbons and the diffuse interstellar bands: a survey. Astrophys. J. 728, 154 (2011).
Witt, A. N. Blue luminescence and extended red emission: possible connections to the diffuse interstellar bands. Proc. Int. Astronom. Union 9, 173–179 (2014).
Draine, B. T. Interstellar dust grains. Annu. Rev. Astron. Astrophys. 41, 241–289 (2003).
Dickinson, C. et al. The state-of-play of anomalous microwave emission (AME) research. New Astron. Rev. 80, 1–28 (2018).
Bakes, E. & Tielens, A. G. G. M. The photoelectric heating mechanism for very small graphitic grains and polycyclic aromatic hydrocarbons. Astrophys. J. 427, 822–838 (1994).
Weingartner, J. C. & Draine, B. T. Photoelectric emission from interstellar dust: grain charging and gas heating. Astrophys. J. Suppl. 134, 263–282 (2001).
Kamp, I. & Dullemond, C. P. The gas temperature in the surface layers of protoplanetary disks. Astrophys. J. 615, 991–999 (2004).
Verstraete, L. The role of PAHs in the physics of the interstellar medium. EAS Publ. Ser. 46, 415–426 (2011).
Hudgins, D. M. & Allamandola, L. J. Steps toward identifying PAHs: A summary of some recent results. IAUS 231, 443–454 (2005).
Sellgren, K., Werner, M. W. & Dinerstein, H. L. Extended near-infrared emission from visual reflection nebulae. Astrophys. J. 271, L13–L17 (1983).
Greenberg, J. M. in Stars and Stellar Systems Vol. 7 (eds Middlehurst, B. M. & Aller, L. H.) 221–364 (Univ. Chicago Press, 1968).
Sellgren, K. The near-infrared continuum emission of visual reflection nebulae. Astrophys. J. 277, 623–633 (1984).
Geballe, T. R., Lacy, J. H., Persson, S. E., McGregor, P. J. & Soifer, B. T. Spectroscopy of the 3 μm emission features. Astrophys. J. 292, 500–505 (1985).
Jourdain de Muizon, M., Geballe, T. R., d’Hendecourt, L. B. & Baas, F. New emission features in the infrared spectra of two IRAS sources. Astrophys. J. 306, L105–L108 (1986).
Joblin, C., Tielens, A. G. G. M., Allamandola, L. J. & Geballe, T. R. Spatial variation of the 3.29 and 3.40 μm emission bands within reflection nebulae and the photochemical evolution of methylated polycyclic aromatic hydrocarbons. Astrophys. J. 458, 610–620 (1996).
Cohen, M., Tielens, A. G. G. M. & Allamandola, L. J. A new emission feature in IRAS spectra and the polycyclic aromatic hydrocarbon spectrum. Astrophys. J. 299, L93–L97 (1985).
Tokunaga, A. T. A summary of the “UIR” bands. ASP Conf. Ser. 124, 149–160 (1997).
Cohen, M. et al. The infrared emission bands. III. Southern IRAS sources. Astrophys. J. 341, 246–269 (1989).
Peeters, E., Allamandola, L. J., Hudgins, D. M., Hony, S. & Tielens, A. G. G. M. The unidentified infrared features after ISO. ASP Conf. Ser. 309, 141–162 (2004).
Moutou, C., Verstraete, L., Léger, A., Sellgren, K., Schmidt, W. & New, P. A. H. mode at 16.4 μm. Astron. Astrophys. 354, L17–L20 (2000).
Schutte, W. A. et al. ISO-SWS observations of infrared absorption bands of the diffuse interstellar medium: the 6.2 μm feature of aromatic compounds. Astron. Astrophys. 337, 261–274 (1998).
Chiar, J. E. et al. The composition and distribution of dust along the line of sight toward the Galactic Center. Astrophys. J. 537, 749–762 (2000).
Peeters, E. et al. The rich 6 to 9 μm spectrum of interstellar PAHs. Astron. Astrophys. 390, 1089–1113 (2002).
Mattila, K. et al. Spectrophotometry of UIR bands in the diffuse emission of the Galactic Disk. Astron. Astrophys. 315, L353–L356 (2000).
Onaka, T., Yamamura, I., Tanabe, T., Roellig, T. L. & Yuen, L. Detection of the mid-infrared unidentified bands in the diffuse galactic emission by IRTS. Publ. Astron. Soc. Jpn 48, L59–L63 (1996).
Tanaka, M. et al. IRTS observation of the unidentified 3.3 μm band in the diffuse galactic emission. Publ. Astron. Soc. Jpn 48, L53–L57 (1996).
Siebenmorgen, R., Prusti, T., Natta, A. & Müller, T. G. Mid infrared emission of nearby Herbig Ae/Be stars. Astron. Astrophys. 361, 258–264 (2006).
Furlan, E. et al. A survey and analysis of Spitzer Infrared Spectrograph spectra of T Tauri stars in Taurus. Astrophys. J. Suppl. 165, 568–605 (2006).
Geers, V. C. et al. C2D Spitzer-IRS spectra of disks around T Tauri stars. II. PAH emission features. Astron. Astrophys. 459, 545–556 (2006).
Seok, J. Y. & Li, A. Polycyclic aromatic hydrocarbons in protoplanetary disks around Herbig Ae/Be and T Tauri stars. Astrophys. J. 835, 291 (2017).
Sandstrom, K. M. et al. The Spitzer spectroscopic survey of the Small Magellanic Cloud (S4MC): probing the physical state of polycyclic aromatic hydrocarbons in a low-metallicity environment. Astrophys. J. 744, 20 (2012).
Hemachandra, D. et al. Mid-infrared spectroscopy of the Andromeda galaxy. Astron. Astrophys. 454, 818–830 (2015).
Boersma, C., Rubin, R. H. & Allamandola, L. J. Spatial analysis of the polycyclic aromatic hydrocarbon features southeast of the Orion Bar. Astrophys. J. 753, 168 (2012).
Boersma, C., Bregman, J. & Allamandola, L. J. Properties of polycyclic aromatic hydrocarbons in the northwest photon dominated region of NGC 7023. III. Quantifying the traditional proxy for PAH charge and assessing its role. Astrophys. J. 806, 121 (2015).
Shannon, M. J., Stock, D. J. & Peeters, E. Interpreting the subtle spectral variations of the 11.2 and 12.7 μm polycyclic aromatic hydrocarbon bands. Astrophys. J. 824, 111 (2016).
Smith, J. D. T. et al. Mid-infrared IRS spectroscopy of NGC 7331: a first look at the Spitzer Infrared Nearby Galaxies Survey (SINGS) legacy. Astrophys. J. Suppl. 154, 199–203 (2004).
Werner, M. W. et al. New infrared emission features and spectral variations in NGC 7023. Astrophys. J. Suppl. 154, 309–314 (2004).
Beintema, D. A. et al. The rich spectrum of circumstellar PAHs. Astron. Astrophys. 315, L369–L372 (1996).
van Kerckhoven, C. et al. The C–C–C bending modes of PAHs: a new emission plateau from 15 to 20 μm. Astrophys. J. Suppl. 357, 1013–1019 (2000).
Cami, J., Bernard-Salas, J., Peeters, E. & Malek, S. E. Detection of C60 and C70 in a young planetary nebula. Science 329, 1180–1182 (2010).
Sellgren, K. et al. C60 in reflection nebulae. Astrophys. J. 722, L54–L57 (2010).
Witteborn, F. C. et al. New emission features in the 11–13 μm region and their relationship to polycyclic aromatic hydrocarbons. Astrophys. J. 341, 270–277 (1989).
Hony, S. et al. The CH out-of-plane bending modes of PAH molecules in astrophysical environments. Astron. Astrophys. 370, 1030–1043 (2001).
Hudgins, D. M. & Allamandola, L. J. Interstellar PAH emission in the 11–14 μm region: new insights from laboratory data and a tracer of ionized PAHs. Astrophys. J. 516, L41–L44 (1999).
Matsuura, M. et al. Spitzer Space Telescope spectra of post-AGB stars in the Large Magellanic Cloud — polycyclic aromatic hydrocarbons at low metallicities. Mon. Not. R. Astron. Soc. 439, 1472–1493 (2014).
Sloan, G. C. et al. Carbon-rich dust past the asymptotic giant branch: aliphatics, aromatics, and fullerenes in the Magellanic Clouds. Astrophys. J. 791, 28 (2014).
Hudgins, D. M., Bauschlicher, J. C. W. & Allamandola, L. J. Variations in the peak position of the 6.2 μm interstellar emission feature: a tracer of N in the interstellar polycyclic aromatic hydrocarbon population. Astrophys. J. 632, 316–332 (2005).
Canelo, C. M., Friaça, A. C. S., Sales, D. A., Pastoriza, M. G. & Ruschel-Dutra, D. Variations in the 6.2 μm emission profile in starburst-dominated galaxies: a signature of polycyclic aromatic nitrogen heterocycles (PANHs)? Mon. Not. R. Astron. Soc. 475, 3746–3763 (2018).
Berné, O. et al. Analysis of the emission of very small dust particles from Spitzer spectro-imagery data using blind signal separation methods. Astron. Astrophys. 469, 575–586 (2007).
Povich, M. S. et al. A Multiwavelength study of M17: the spectral energy distribution and PAH emission morphology of a massive star formation region. Astrophys. J. 660, 346–362 (2007).
Elbaz, D., Le Floc’h, E., Dole, H. & Marcillac, D. Observational evidence for the presence of PAHs in distant luminous infrared galaxies using ISO and Spitzer. Astron. Astrophys. 434, L1–L4 (2004).
Yan, L. et al. Spitzer detection of polycyclic aromatic hydrocarbon and silicate dust features in the mid-infrared spectra of z ~ 2 ultraluminous infrared galaxies. Astrophys. J. 628, 604–610 (2005).
Lutz, D. et al. Mid-infrared spectroscopy of two luminous submillimeter galaxies at z ~ 2.8. Astrophys. J. 625, L83–L86 (2005).
Siana, B. et al. Detection of far-infrared and polycyclic aromatic hydrocarbon emission from the Cosmic Eye: probing the dust and star formation of Lyman break galaxies. Astrophys. J. 698, 1273–1281 (2009).
Riechers, D. A. et al. Polycyclic aromatic hydrocarbon and mid-infrared continuum emission in a z > 4 submillimeter galaxy. Astrophys. J. 786, 31 (2014).
Bernstein, M. P. et al. UV irradiation of polycyclic aromatic hydrocarbons in ices: production of alcohols, quinones, and ethers. Science 283, 1158–1138 (1999).
Kwok, S. Complex organics in space from Solar System to distant galaxies. Astron. Astrophys. Rev. 24, 8 (2016).
Shipley, H. V. et al. A new star formation rate calibration from polycyclic aromatic hydrocarbon emission features and application to high-redshift galaxies. Astrophys. J. 818, 60 (2016).
Pope, A. et al. Mid-infrared spectral diagnosis of submillimeter galaxies. Astrophys. J. 675, 1171–1193 (2008).
Calzetti, D. et al. The calibration of mid-infrared star formation rate indicators. Astrophys. J. 666, 870–895 (2007).
Xie, Y. & Ho, L. C. A new calibration of star formation rate in galaxies based on polycyclic aromatic hydrocarbon emission. Astrophys. J. 884, 136 (2019).
Kaneda, H. et al. Unbiased large spectroscopic surveys of galaxies selected by SPICA using dust bands. Publ. Astron. Soc. Aust. 34, e059 (2017).
Kaneda, H., Onaka, T. & Sakon, I. Detection of PAH emission features from nearby elliptical galaxies with the Spitzer Infrared Spectrograph. Astrophys. J. 632, L83–L86 (2005).
Kaneda, H. et al. Properties of polycyclic aromatic hydrocarbons in local elliptical galaxies revealed by the Infrared Spectrograph on Spitzer. Astrophys. J. 684, 270–281 (2008).
Vega, O. et al. Unusual PAH emission in nearby early-type galaxies: a signature of an intermediate-age stellar population? Astrophys. J. 721, 1090–1104 (2010).
Irwin, J. A. & Madden, S. C. Discovery of PAHs in the halo of NGC 5907. Astron. Astrophys. 445, 123–141 (2005).
Engelbracht, C. W. et al. Extended mid-infrared aromatic feature emission in M82. Astrophys. J. 642, 127–132 (2006).
Beirão, P. et al. Spatially resolved Spitzer-IRS spectral maps of the superwind in M82. Mon. Not. R. Astron. Soc. 451, 2640–2655 (2015).
Yamagishi, M. et al. AKARI near-infrared spectroscopy of the aromatic and aliphatic hydrocarbon emission features in the galactic superwind of M82. Astron. Astrophys. 541, A10 (2012).
Schutte, W. A., Tielens, A. G. G. M. & Allamandola, L. J. Theoretical modeling of the infrared fluorescence from interstellar polycyclic aromatic hydrocarbons. Astrophys. J. 415, 397–414 (1993).
Bernstein, M. P., Sandford, S. A. & Allamandola, L. J. Hydrogenated polycyclic aromatic hydrocarbons and the 2940 and 2850 wavenumber (3.40 and 3.51 μm) infrared emission features. Astrophys. J. 472, L127–L130 (1996).
Sandford, S. A. The infrared spectra of polycyclic aromatic hydrocarbons with excess peripheral H atoms (Hn-PAHs) and their relation to the 3.4 and 6.9 μm PAH emission features. Astrophys. J. Suppl. 205, 8 (2013).
Steglich, M. et al. The abundances of hydrocarbon functional groups in the interstellar medium inferred from laboratory spectra of hydrogenated and methylated polycyclic aromatic hydrocarbons. Astrophys. J. Suppl. 208, 26 (2013).
Yang, X. J., Li, A. & Glaser, R. Superhydrogenated polycyclic aromatic hydrocarbon molecules: vibrational spectra in the infrared. Astrophys. J. Suppl. 247, 1 (2020).
Baker, J. R., Allamandola, L. J. & Tielens, A. G. G. M. Anharmonicity and the interstellar polycyclic aromatic hydrocarbon infrared emission spectrum. Astrophys. J. 315, L61–L65 (1987).
Maltseva, E. et al. High-resolution IR absorption spectroscopy of polycyclic aromatic hydrocarbons in the 3 μm region: role of periphery. Astrophys. J. Suppl. 831, 58 (2016).
Li, A. & Draine, B. T. The carriers of the interstellar unidentified infrared emission features: aromatic or aliphatic? Astrophys. J. 760, L35 (2012).
Yang, X. J., Glaser, R., Li, A. & Zhong, J. X. The carriers of the interstellar unidentified infrared emission features: constraints from the interstellar C–H stretching features at 3.2–35 μm. Astrophys. J. 776, 110 (2013).
Yang, X. J., Glaser, R., Li, A. & Zhong, J. X. The carriers of the unidentified infrared emission features: clues from polycyclic aromatic hydrocarbons with aliphatic sidegroups. New Astron. Rev. 77, 1–22 (2016).
Yang, X. J., Glaser, R., Li, A. & Zhong, J. X. On the aliphatic versus aromatic content of the carriers of the ‘unidentified’ infrared emission features. Mon. Not. R. Astron. Soc. 462, 1551–1562 (2016).
Micelotta, E. R., Jones, A. P. & Tielens, A. G. G. M. Polycyclic aromatic hydrocarbon processing in interstellar shocks. Astron. Astrophys. 510, A36 (2010).
Shannon, M. J., Peeters, E., Cami, J. & Blommaert, J. A. D. L. Polycyclic aromatic hydrocarbon emission toward the galactic bulge. Astrophys. J. 855, 32 (2018).
Rand, R. J., Wood, K. & Benjamin, R. A. Infrared spectroscopy of the diffuse ionized halo of NGC 891. Astrophys. J. 680, 263–275 (2008).
Sanders, D. B. & Mirabel, I. F. Luminous infrared galaxies. Annu. Rev. Astron. Astrophys. 34, 749–792 (1996).
Higdon, S. J., Higdon, J. L. & Marshall, J. First detection of PAHs and warm molecular hydrogen in tidal dwarf galaxies. Astrophys. J. 640, 768–783 (2006).
Haan, S. et al. Spitzer IRS spectral mapping of the Toomre sequence: spatial variations of PAH, gas, and dust properties in nearby major mergers. Astrophys. J. Suppl. 197, 27 (2011).
Murata, K. L. et al. A relationship of polycyclic aromatic hydrocarbon features with galaxy merger in star-forming galaxies at z < 0.2. Mon. Not. R. Astron. Soc. 472, 39–50 (2017).
Onaka, T. et al. Near-infrared to mid-infrared observations of galaxy mergers: NGC 2782 and NGC 7727. Astrophys. J. 853, 31 (2018).
Voit, G. M. Destruction and survival of polycyclic aromatic hydrocarbons in active galaxies. Mon. Not. R. Astron. Soc. 258, 841–848 (1992).
Siebenmorgen, R., Krügel, E. & Spoon, H. W. W. Mid-infrared emission of galactic nuclei. TIMMI2 versus ISO observations and models. Astron. Astrophys. 414, 123–139 (2004).
Roche, P. F., Aitken, D. K., Smith, C. H. & Ward, M. J. An atlas of mid-infrared spectra of galaxy nuclei. Mon. Not. R. Astron. Soc. 248, 606–629 (1991).
Genezel, R. et al. What powers ultraluminous IRAS galaxies? Astrophys. J. 498, 579–605 (1998).
Esquej, C. W. et al. Nuclear star formation activity and black hole accretion in nearby Seyfert galaxies. Astrophys. J. 780, 86–100 (2014).
Jensen, J. J. et al. PAH features within few hundred parsecs of active galactic nuclei. Mon. Not. R. Astron. Soc. 470, 3071–3094 (2017).
Tommasin, S. et al. Spitzer-IRS high-resolution spectroscopy of the 12 μm Seyfert galaxies. II. Results for the complete data set. Astrophys. J. 709, 1257–1283 (2010).
Murata, K. L. et al. Evolution of the fraction of clumpy galaxies at 0.2 < z < 1.0 in the COSMOS field. Astrophys. J. 786, 15 (2014).
Maragkoudakis, A. et al. PAHs and star formation in the H ii regions of nearby galaxies M83 and M33. Mon. Not. R. Astron. Soc. 481, 5370–5393 (2018).
O’Dowd, M. J. et al. Polycyclic aromatic hydrocarbons in galaxies at z ~ 0.1: the effect of star formation and active galactic nuclei. Astrophys. J. 705, 885–898 (2009).
Diamond-Stanic, A. M. & Rieke, G. H. The effect of active galactic nuclei on the mid-infrared aromatic features. Astrophys. J. 724, 140–153 (2010).
Wu, Y. et al. Infrared luminosities and aromatic features in the 24 μm flux-limited sample of 5MUSES. Astrophys. J. 723, 895–914 (2010).
Allamandola, L. J., Hudgins, D. M. & Sandford, S. A. Modeling the unidentified infrared emission with combinations of polycyclic aromatic hydrocarbons. Astrophys. J. 511, L115–L119 (1999).
Bauschlicher, C. W., Ricca, A., Boersma, C. & Allamandola, L. J. The NASA Ames PAH IR spectroscopic database: computational version 3.00 with updated content and the introduction of multiple scaling factors. Astrophys. J. Suppl. 234, 32 (2018).
Galliano, F., Madden, S. C., Tielens, A. G. G. M., Peeters, E. & Jones, A. P. Variations of the mid-IR aromatic features inside and among galaxies. Astrophys. J. 679, 310–345 (2008).
Mattioda, A. L., Hudgins, D. M., Bauschlicher, C. W., Rosi, M. & Allamandola, L. J. Infrared spectroscopy of matrix-isolated polycyclic aromatic compounds and their ions. 6. Polycyclic aromatic nitrogen heterocycles. J. Phys. Chem. A 107, 1486–1498 (2003).
Mattioda, A. L. et al. Infrared spectroscopy of matrix-isolated neutral polycyclic aromatic nitrogen heterocycles: the acridine series. Spectrochim. Acta A 181, 286–308 (2017).
Thuan, T. X., Sauvage, M. & Madden, S. Dust in an extremely metal-poor galaxy: mid-infrared observations of SBS 0335−052. Astrophys. J. 516, 783–787 (1999).
Houck, J. R. et al. The extraordinary mid-infrared spectrum of the blue compact dwarf galaxy SBS 0335−052. Astrophys. J. Suppl. 154, 211–214 (2004).
Madden, S. C., Galliano, F., Jones, A. P. & Sauvage, M. ISM properties in low-metallicity environments. Astron. Astrophys. 446, 877–896 (2006).
Wu, Y. et al. Mid-infrared properties of low-metallicity blue compact dwarf galaxies from the Spitzer Infrared Spectrograph. Astrophys. J. 639, 157–172 (2006).
Hunt, L. K., Thuan, T. X., Izotov, Y. I. & Sauvage, M. The Spitzer view of low-metallicity star formation. III. Fine-structure lines, aromatic features, and molecules. Astrophys. J. 712, 164–187 (2010).
Engelbracht, C. W. et al. Metallicity effects on mid-infrared colors and the 8 μm PAH emission in galaxies. Astrophys. J. 628, 29–32 (2005).
Draine, B. T. et al. Dust masses, PAH abundances, and starlight intensities in the SINGS galaxy sample. Astrophys. J. 663, 866–894 (2007).
Asplund, M., Grevesse, N., Sauval, A. J. & Scott, P. The chemical composition of the Sun. Annu. Rev. Astron. Astrophys. 47, 481–522 (2009).
Gordon, K. D. et al. The behavior of the aromatic features in M101 H ii regions: evidence for dust processing. Astrophys. J. 682, 336–354 (2008).
Wu, R., Hogg, D. W. & Moustakas, J. The aromatic features in very faint dwarf galaxies. Astrophys. J. 730, 111 (2011).
Seok, J. Y., Hirashita, H. & Asano, R. S. Formation history of polycyclic aromatic hydrocarbons in galaxies. Mon. Not. R. Astron. Soc. 439, 2186–2196 (2014).
Galliano, F., Dwek, E. & Chanial, P. Stellar evolutionary effects on the abundances of polycyclic aromatic hydrocarbons and supernova-condensed dust in galaxies. Astrophys. J. 672, 214–243 (2008).
Shivaei, I. et al. The MOSDEF survey: Metallicity dependence of PAH emission at high redshift and implications for 24 μm inferred IR luminosities and star formation rates at z ~ 2. Astrophys. J. 837, 157 (2017).
Jackson, D. C. et al. Hot dust and polycyclic aromatic hydrocarbon emission at low metallicity: a Spitzer survey of Local Group and other nearby dwarf galaxies. Astrophys. J. 646, 192–204 (2006).
Tappe, A., Rho, J. & Reach, W. T. Shock processing of interstellar dust and polycyclic aromatic hydrocarbons in the supernova remnant N132D. Astrophys. J. 653, 267–279 (2006).
Seok, J. Y., Koo, B.-C. & Onaka, T. Detection of the 3.3 μm aromatic feature in the supernova remnant N49 with AKARI. Astrophys. J. 744, 160 (2012).
Andersen, M. et al. Dust processing in supernova remnants: Spitzer MIPS spectral energy distribution and Infrared Spectrograph observations. Astrophys. J. 742, 7 (2011).
Andrews, H. et al. PAH emission at the bright locations of PDRs: the grand PAH hypothesis. Mon. Not. R. Astron. Soc. 807, 99 (2015).
Kwok, S. & Zhang, Y. Mixed aromatic-aliphatic organic nanoparticles as carriers of unidentified infrared emission features. Nature 479, 80–83 (2011).
Salama, F., Joblin, C. & Allamandola, L. J. Neutral and ionized PAHs: contribution to the interstellar extinction. Planet. Space Sci. 43, 1165–1173 (1995).
Clayton, G. C. et al. The role of polycyclic aromatic hydrocarbons in ultraviolet extinction. I. Probing small molecular polycyclic aromatic hydrocarbons. Astrophys. J. 592, 947–952 (2003).
Buss, R. H., Tielens, A. G. G. M. & Snow, T. P. The mid-infrared spectrum of the carbon star HD 38218 and its possible relation to polycyclic aromatic hydrocarbons. Astrophys. J. 372, 281–290 (1991).
Speck, A. K. & Barlow, M. J. UIR bands in carbon star spectra. Astrophys. Space. Sci. 251, 115–121 (1997).
Boersma, C., Hony, S. & Tielens, A. G. G. M. UIR bands in the ISO SWS spectrum of the carbon star TU Tauri. Astron. Astrophys. 447, 213–220 (2006).
Sloan, G. C. et al. The unusual hydrocarbon emission from the early carbon star HD 100764: the connection between aromatics and aliphatics. Astrophys. J. 664, 1144–1153 (2007).
Li, A. & Draine, B. T. Do the infrared emission features need ultraviolet excitation? The polycyclic aromatic hydrocarbon model in UV-poor reflection nebulae. Astrophys. J. 572, 232–237 (2002).
Mattioda, A. L., Hudgins, D. M. & Allamandola, L. J. Experimental near-infrared spectroscopy of polycyclic aromatic hydrocarbons between 0.7 and 2.5 μm. Astrophys. J. 629, 1188–1210 (2005).
Uchida, K. I., Sellgren, K. & Werner, M. W. Do the infrared emission features need ultraviolet excitation? Astrophys. J. 493, L109–L112 (1998).
Jura, M. et al. Polycyclic aromatic hydrocarbons orbiting HD 233517, an evolved oxygen-rich red giant. Astrophys. J. 637, L45–L47 (2006).
Sandstrom, K. M. et al. The Spitzer survey of the Small Magellanic Cloud (S3MC): insights into the life cycle of polycyclic aromatic hydrocarbons. Astrophys. J. 715, 701–723 (2010).
Paradis, D. et al. Spatial variations of dust abundances across the Large Magellanic Cloud. Astron. J. 138, 196–209 (2009).
Lau, R. M., Werner, M. W., Sahai, R. & Ressler, M. E. Evidence from SOFIA imaging of polycyclic aromatic hydrocarbon formation along a recent outflow in NGC 7027. Astrophys. J. 833, 115 (2016).
Xie, Y., Ho, L. C., Li, A. & Shangguan, J. Y. The widespread presence of nanometer-size dust grains in the interstellar medium of galaxies. Astrophys. J. 867, 91 (2018).
Kwok, S., Volk, K. & Bernath, P. On the origin of infrared plateau features in proto-planetary nebulae. Astrophys. J. 554, L87–L90 (2001).
Uchida, K. I., Sellgren, K., Werner, M. W. & Houdashelt, M. L. Infrared Space Observatory mid-infrared spectra of reflection nebulae. Astrophys. J. 530, 817–833 (2000).
Rapacioli, M., Joblin, C. & Boissel, P. Spectroscopy of polycyclic aromatic hydrocarbons and very small grains in photodissociation regions. Astron. Astrophys. 429, 193–204 (2005).
Peeters, E. et al. The PAH emission characteristics of the reflection nebula NGC 2023. Astrophys. J. 836, 198 (2017).
Xie, Y., Ho, L. C., Li, A. & Shangguan, J. Y. A New technique for measuring polycyclic aromatic hydrocarbon emission in different environments. Astrophys. J. 860, 154 (2018).
Cruz-Diaz, G. A. et al. PAH products and processing by different energy sources. Astrophys. J. 882, 44 (2019).
An, J. H. & Sellgren, K. Spatial separation of the 3.29 μm emission feature and associated 2 μm continuum in NGC 7023. Astrophys. J. 599, 312–323 (2003).
Geballe, T. R. et al. Detection of the overtone of the 3.3 μm emission feature in IRAS 21282+5050. Astrophys. J. 434, L15–L18 (1994).
Chen, T., Luo, Y. & Li, A. The infrared bands of polycyclic aromatic hydrocarbons in the 1.6–17 μm wavelength region. Astron. Astrophys. 632, A71 (2019).
Draine, B. T. Can dust explain variations in the D/H ratio? ASP Conf. Ser. 348, 58–69 (2006).
Peeters, E. et al. Deuterated interstellar polycyclic aromatic hydrocarbons. Astrophys. J. 604, 252–257 (2004).
Onaka, T. et al. Search for the infrared emission features from deuterated interstellar polycyclic aromatic hydrocarbons. Astrophys. J. 780, 114 (2014).
Doney, K. D., Candian, A., Mori, T., Onaka, T. & Tielens, A. G. G. M. Deuterated polycyclic aromatic hydrocarbons: revisited. Astron. Astrophys. 586, 65–74 (2016).
Peeters, E., Tielens, A. G. G. M., Boogert, A. C. A., Hayward, T. L. & Allamandola, L. J. The prominent dust emission feature near 8.9 μm in four H ii regions. Astrophys. J. 620, 774–785 (2005).
Verstraete, L. et al. The aromatic infrared bands as seen by ISO-SWS: probing the PAH model. Astron. Astrophys. 372, 981–997 (2001).
van Diedenhoven, B. et al. The profiles of the 3–12 μm polycyclic aromatic hydrocarbon features. Astron. Astrophys. 611, 928–939 (2004).
Schütz, O., Meeus, G., Sterzik, M. F. & Peeters, E. Mid-IR observations of circumstellar disks. Part III. A mixed sample of PMS stars and Vega-type objects. Astron. Astrophys. 507, 261–276 (2009).
Sloan, G. C. et al. Mid-infrared spectra of polycyclic aromatic hydrocarbon emission in Herbig Ae/Be stars. Astrophys. J. 632, 956–963 (2005).
Ingalls, J. G. et al. Spitzer Infrared Spectrograph detection of molecular hydrogen rotational emission towards translucent clouds. Astrophys. J. 743, 174 (2011).
Mathis, J. S., Mezger, P. G. & Panagia, N. Interstellar radiation field and dust temperatures in the diffuse interstellar matter and in giant molecular clouds. Astron. Astrophys. 128, 212–229 (1983).
Berné, O. & Tielens, A. G. G. M. Formation of buckminsterfullerene (C60) in interstellar space. Proc. Natl Acad. Sci. USA 109, 401–406 (2012).
García-Hernández, D. A. et al. The formation of fullerenes: clues from new C60, C70, and (possible) planar C24 detections in Magellanic Cloud planetary nebulae. Astrophys. J. 737, L30 (2011).
Li, Q., Li, A. & Jiang, B. W. How much graphene in space? Mon. Not. R. Astron. Soc. 490, 3875–3881 (2019).
Chen, T. & Li, A. Synthesizing carbon nanotubes in space. Astron. Astrophys. 631, A54 (2019).
Derenne, S. & Robert, F. Model of molecular structure of the insoluble organic matter isolated from Murchison meteorite. Meteorit. Planet. Sci. 45, 1461–1475 (2010).
Acknowledgements
I dedicate this article to the 60th anniversary of the Department of Astronomy of Beijing Normal University, the 2nd astronomy programme in the modern history of China. I thank B. T. Draine, L. C. Ho, M. Karouzos and X. J. Yang for useful comments and suggestions. I thank L. Armus, P. Beirão, J. G. Ingalls, H. Kaneda, D. Lutz, K. Mattila, D. A. Riechers, B. Siana, O. Vega, M. Yamagishi and L. Yan for providing the PAH spectra shown in Figs. 1–4. This work is supported in part by NASA grants 80NSSC19K0572 and 80NSSC19K0701.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The author declares no competing interests.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Li, A. Spitzer’s perspective of polycyclic aromatic hydrocarbons in galaxies. Nat Astron 4, 339–351 (2020). https://doi.org/10.1038/s41550-020-1051-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41550-020-1051-1
This article is cited by
-
Carbon-chain chemistry in the interstellar medium
Astrophysics and Space Science (2024)
-
Efficient stabilization of cyanonaphthalene by fast radiative cooling and implications for the resilience of small PAHs in interstellar clouds
Nature Communications (2023)
-
Light from cosmic dawn hints at how interstellar dust is made
Nature (2023)
-
Spatial variations in aromatic hydrocarbon emission in a dust-rich galaxy
Nature (2023)
-
Low-temperature nitrogen-bearing polycyclic aromatic hydrocarbon formation routes validated by infrared spectroscopy
Nature Astronomy (2022)